KMID : 1059519900340050396
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Journal of the Korean Chemical Society 1990 Volume.34 No. 5 p.396 ~ p.403
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A Diamond-like Film Formation from (CH4 £« H2) Gas Mixture with the LPCVD Apparatus
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Kim Sang-Kyun
Choy Jin-Ho Choo Kwang-Yul
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Abstract
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We describe how to design and construct a LPCVD (Low Pressure Chemical Vapor Deposition) apparatus which can be applicable to the study of reaction mechanism in general CVD experiments. With this apparatus we have attempted to make diamond like carbon films on the p-type (111) Si wafer from (H2 £« CH4) gas mixtures. Two different methods have been tried to get products. (1)The experiment was carried out in the reactor with two different inlet gas tubes. One coated with phosphoric acid was used for supplying microwave discharged hydrogen gas stream, and methane has been passed through the other tube without the microwave discharge. In this method we got only amorphous carbon cluster products. (2) The gas mixture (H2 £« CH4) has been passed through the discharge tube with the Si wafer located in and/or near the microwave plasma. In this case diamond-like carbon products could be obtained.
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KEYWORD
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